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some places in Berlin that I like to go to (all Google links):

MUST SEE

Berliner Mauer Gedenkstätte

CAFES

nearby:
Jubel | Patisserie
Prenzlauer Berg:
Meierei  | excellent ‚Apfelstrudel‘!
Mitte:
Du Bonheur | Patisserie
Kreuzberg:
Cafe 9
Bonanza Coffee Roasters
Charlottenburg:
Cafe Einstein | Vienna Style Kaffehaus

FOOD

nearby:
L’Èpicerie |
french wine, groceries etc.
Goldhahn & Sampson | fine groceries, wine, coffee & cook books 
Friedrichshain:
Frischeparadies | fresh fish and anything a foodie wishes. Try the Bouillabaisse!
Kreuzberg:
Markthalle Neun | checkout the website for opening hours and events
different locations:
Zeit für Brot | best bread in town

EAT OUT

nearby:
Mami Camila | very good pizza in Hufelandstrasse
Gasthaus Alt Wien | best ‚Schnitzel‘ possible!
Mitte:
Shiso Burger
YamYam | korean food
Charlottenburg:
Heno Heno | japanese Bistro

CULTURE

Mitte:
Dussmann | books, Music and CD
Boulez Saal | chambermusic hall

SHOPPING

Charlottenburg:
KaDeWe | department store
Manufactum | quality things like 100 years ago
Flee market | on Arkonaplatz on Saturday/Sunday
Boesner | artist supplies
Modulor | materials and artist supplies

nearby:
Wollmeister | everything Merino